@blucrane Hello! The reason it's recommended that you don't test with first morning urine (FMU) but with second morning urine (at 9-10am) is that for most folks, the hormone you're trying to catch doesn't peak until later in the morning. But there are other things that influence how concentrated LH is in your urine, most significantly, the amount of water you take in -- the more water you drink, the more you're diluting your urine, including how much LH seems to be in it. That's why it's recommended that you don't drink too much water during the day while you're testing (limit water intake 3-4 hours before the test), so that you don't dilute your urine too much.
I personally always drink a lot of water throughout the day, and when I don't drink enough, I get these annoyingly lasting dehydration headaches, so my most reliably concentrated urine is FMU (after many nighttime hours of not drinking water) which is why I would always test it. If you are not like me and can sustain not drinking a lot of water during the days while you test, then follow the official recommendations and test somewhere in the window from 9-10am to about 6-8pm while limiting your water intake for 3-4 hours prior to testing.
The apps you're using must have an ovulation day predicted for you. (If not, try the app Clue for instance.) If you've never tested before, you might want to start testing several days before this predicted ovulation day. Honestly, the availability of the super cheap testing strips removes the mindset of scarcity and allows you to test as early as you like, maybe even on a uselessly early like, say, 6-7 days past ovulation, and test once a day, say, with the morning urine to see what your baseline level of LH is. I used the Premom app to take photos of the strips and it gives you a numerical value for the readout. For my low-LH days, the baseline could have been somewhere around 0.05-0.2 or so (but that's just my body).
Then sometime before your ovulation, you'll start seeing a rise in LH. For me, I'd start paying attention when LH would start registering at 0.4-0.5, that would tell me I should start testing more often. There are so many cheap LH strips out there (I personally used Easy@Home ones) that when I saw a tick up in the numbers, I would just start testing 3 times a day at times after I didn't drink too much water (for me that was FMU, then at noon when returning from the morning walk, and then again at 6pm after the evening walk).
Every person has a different surge profile, either "slow" (over a course of 2-3 days) or "fast" (in less than a day), and that's something that you'll be able to figure out only after testing for several months in a row. My surge was slowish, so it took 2-3 days overall. During those days, I tested anywhere from 3 to 5 times, sometimes as late as 10pm, which is also outside the recommended window, but in my case, it was occasionally (rarely!) the time of my peak. From what I recall, the test line started getting darker than the control line when the LH values reached about 1.0, and in my case, they could stay above 1.0 for about 1.5 days, reaching as high as 1.6 or 1.7 at their peak. But that is just my pattern. You will figure out yours once you start testing.
An important thing to figure out is how you are your partner are about having on-demand sex and to come up with a system that would be sustainable for the two of you for months on end (since it might take a while to get pregnant). We really prioritized keeping the enjoyment of spontaneous sex throughout the month (2ish times a week tends to be our sweet spot) and we tried to never force ourselves to have sex more than 3 (rarely 4) times during the fertile window. I read about couples who had sex every day for 8 days in a row! That would exhaust us and not be sustainable for 6ish+ months, but ymmv. I do suggest really reflecting on how much sex might feel like too much because you don't want to unintentionally kill off your mutual libido while TTC, to the extent that that kind of thing can be avoided. Maybe you two would enjoy having 8 days of sex in a row months on end, and if so, go for it! Only you can answer that question for yourself.
But in our case and with my surge pattern, we started having sex when I saw my LH numbers get into 0.5-0.7 range and then try to have sex 3 times 24-36 hours apart, sometimes alternating morning and evening sex.
My mind has not been steeping in TTC thoughts for a while, but I've read different (and conflicting!) things about what defines the start of the "surge." Where I've landed in my understanding is that the start of the surge is when your baseline numbers start ticking up (so I guess that would be when mine went from being 0.05-0.2 to being 0.4-0.5). The "peak" is... well, what it sounds like. Because of all that stuff about wanting sperm there before the egg arrives, you should start having sex once you detect the surge which is before the peak. Bodies differ in when they actually release the egg after the surge or peak and the only way to know for sure when you ovulated is by temping over several months. We never bothered and still did fine. I did pay attention to my cervical mucus to try to have another indicator of ovulation approaching, and that's probably a worthwhile low-effort sort of thing to do for anyone TTC.
Anyway, I know this is a lot of words but hope it's at least somewhat helpful. Best of luck to you